The Library collection of roughly 200,000 books, pamphlets, maps and microform units covers all areas and disciplines. There is an emphasis on the socio-economic development and history of sub-Saharan Africa, with special emphases (reflecting faculty interests) on Ethiopia/Eritrea, Zimbabwe, South Africa, the Sahel region of West Africa, and Nigeria (especially the Eastern Region).

Materials related to the Rivonia Trial include:
- A number of video recordings relating to the life story of Nelson Mandela and thus mentioning the Rivonia Trial in the Audio-Visual Materials on Africa
-Microform and photocopies of Kathrada Collection (originals at UWC-Robben Island Mayibuye Centre) in Special Collections. Over 100 fiche in 13 boxes. DT1949.K38A4 1996; also on film: SPEC COLL RARE BOOKS XX 27823 Microfilm. Guide (1995) available at DT1949.K38S35 1995
-The Voice of Nelson Mandela (SABC, 1999), which includes extracts from the Statement from the Dock. In general library holdings (MSU DIGITAL/MEDIA AUDIODISC, 4 WEST - PT1974 .M36 1999 Audio disc)